Time-resolved UV-visible spectroelectrochemistry using transparent 3D-mesoporous nanocrystalline ITO electrodes.
Identifieur interne : 001071 ( Main/Exploration ); précédent : 001070; suivant : 001072Time-resolved UV-visible spectroelectrochemistry using transparent 3D-mesoporous nanocrystalline ITO electrodes.
Auteurs : RBID : pubmed:21127815English descriptors
- KwdEn :
- MESH :
- chemical , chemistry : Peroxidases, Tin Compounds.
- chemical , metabolism : Peroxidases.
- methods : Spectrophotometry, Ultraviolet.
- Adsorption, Electrochemistry, Electrodes, Electron Transport, Microscopy, Electron, Scanning, Oxidation-Reduction, Porosity, Time Factors.
Abstract
Efficient and rapid adsorption of microperoxidase 11 within a highly porous ITO thin film (200 nm) prepared by glancing angle deposition was achieved. Adsorbed redox molecules were reversibly and rapidly reduced throughout the 3D-conductive matrix in ca. 50 ms, allowing the heterogeneous electron transfer rate to be determined by derivative cyclic voltabsorptometry.
DOI: 10.1039/c0cc04154h
PubMed: 21127815
Links toward previous steps (curation, corpus...)
Le document en format XML
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<author><name sortKey="Renault, Christophe" uniqKey="Renault C">Christophe Renault</name>
<affiliation wicri:level="3"><nlm:affiliation>Laboratoire d'Electrochimie Moléculaire, Université Paris Diderot, UMR CNRS 7591, 15, rue Jean-Antoine de Baïf, 75205 Paris Cedex 13, France.</nlm:affiliation>
<country xml:lang="fr">France</country>
<wicri:regionArea>Laboratoire d'Electrochimie Moléculaire, Université Paris Diderot, UMR CNRS 7591, 15, rue Jean-Antoine de Baïf, 75205 Paris Cedex 13</wicri:regionArea>
<placeName><region type="region" nuts="2">Île-de-France</region>
<settlement type="city">Paris</settlement>
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</author>
<author><name sortKey="Harris, Kenneth D" uniqKey="Harris K">Kenneth D Harris</name>
</author>
<author><name sortKey="Brett, Michael J" uniqKey="Brett M">Michael J Brett</name>
</author>
<author><name sortKey="Balland, Veronique" uniqKey="Balland V">Véronique Balland</name>
</author>
<author><name sortKey="Limoges, Benoit" uniqKey="Limoges B">Benoît Limoges</name>
</author>
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<publicationStmt><date when="2011">2011</date>
<idno type="doi">10.1039/c0cc04154h</idno>
<idno type="RBID">pubmed:21127815</idno>
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<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Adsorption</term>
<term>Electrochemistry</term>
<term>Electrodes</term>
<term>Electron Transport</term>
<term>Microscopy, Electron, Scanning</term>
<term>Oxidation-Reduction</term>
<term>Peroxidases (chemistry)</term>
<term>Peroxidases (metabolism)</term>
<term>Porosity</term>
<term>Spectrophotometry, Ultraviolet (methods)</term>
<term>Time Factors</term>
<term>Tin Compounds (chemistry)</term>
</keywords>
<keywords scheme="MESH" type="chemical" qualifier="chemistry" xml:lang="en"><term>Peroxidases</term>
<term>Tin Compounds</term>
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<keywords scheme="MESH" type="chemical" qualifier="metabolism" xml:lang="en"><term>Peroxidases</term>
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</keywords>
<keywords scheme="MESH" xml:lang="en"><term>Adsorption</term>
<term>Electrochemistry</term>
<term>Electrodes</term>
<term>Electron Transport</term>
<term>Microscopy, Electron, Scanning</term>
<term>Oxidation-Reduction</term>
<term>Porosity</term>
<term>Time Factors</term>
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<front><div type="abstract" xml:lang="en">Efficient and rapid adsorption of microperoxidase 11 within a highly porous ITO thin film (200 nm) prepared by glancing angle deposition was achieved. Adsorbed redox molecules were reversibly and rapidly reduced throughout the 3D-conductive matrix in ca. 50 ms, allowing the heterogeneous electron transfer rate to be determined by derivative cyclic voltabsorptometry.</div>
</front>
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<Day>28</Day>
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<DateCompleted><Year>2011</Year>
<Month>05</Month>
<Day>10</Day>
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<JournalIssue CitedMedium="Internet"><Volume>47</Volume>
<Issue>6</Issue>
<PubDate><Year>2011</Year>
<Month>Feb</Month>
<Day>14</Day>
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<Title>Chemical communications (Cambridge, England)</Title>
<ISOAbbreviation>Chem. Commun. (Camb.)</ISOAbbreviation>
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<ArticleTitle>Time-resolved UV-visible spectroelectrochemistry using transparent 3D-mesoporous nanocrystalline ITO electrodes.</ArticleTitle>
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<Abstract><AbstractText>Efficient and rapid adsorption of microperoxidase 11 within a highly porous ITO thin film (200 nm) prepared by glancing angle deposition was achieved. Adsorbed redox molecules were reversibly and rapidly reduced throughout the 3D-conductive matrix in ca. 50 ms, allowing the heterogeneous electron transfer rate to be determined by derivative cyclic voltabsorptometry.</AbstractText>
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<AuthorList CompleteYN="Y"><Author ValidYN="Y"><LastName>Renault</LastName>
<ForeName>Christophe</ForeName>
<Initials>C</Initials>
<Affiliation>Laboratoire d'Electrochimie Moléculaire, Université Paris Diderot, UMR CNRS 7591, 15, rue Jean-Antoine de Baïf, 75205 Paris Cedex 13, France.</Affiliation>
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<Author ValidYN="Y"><LastName>Harris</LastName>
<ForeName>Kenneth D</ForeName>
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<Author ValidYN="Y"><LastName>Brett</LastName>
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<ChemicalList><Chemical><RegistryNumber>0</RegistryNumber>
<NameOfSubstance>Tin Compounds</NameOfSubstance>
</Chemical>
<Chemical><RegistryNumber>71243-84-0</RegistryNumber>
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<Chemical><RegistryNumber>EC 1.11.1.-</RegistryNumber>
<NameOfSubstance>Peroxidases</NameOfSubstance>
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<Chemical><RegistryNumber>EC 1.11.1.-</RegistryNumber>
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<MeshHeading><DescriptorName MajorTopicYN="N">Electron Transport</DescriptorName>
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<MeshHeading><DescriptorName MajorTopicYN="N">Microscopy, Electron, Scanning</DescriptorName>
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<MeshHeading><DescriptorName MajorTopicYN="N">Oxidation-Reduction</DescriptorName>
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<MeshHeading><DescriptorName MajorTopicYN="N">Peroxidases</DescriptorName>
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<QualifierName MajorTopicYN="N">metabolism</QualifierName>
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<MeshHeading><DescriptorName MajorTopicYN="N">Time Factors</DescriptorName>
</MeshHeading>
<MeshHeading><DescriptorName MajorTopicYN="N">Tin Compounds</DescriptorName>
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